(1) Determine CO₂ emissions from each stack (except flare stacks) according to the Tier 4 Calculation Methodology requirements in subpart C of this part.

(2) For each stack (except flare stacks) that includes emissions from combustion of petrochemical process off-gas, calculate CH₄ and N₂O emissions in accordance with subpart C of this part (use Equation C-10 and the “fuel gas” emission factors in Table C-2 of subpart C of this part).

(3) For each flare, calculate CO₂, CH₄, and N₂O emissions using the methodology specified in § 98.253(b)(1) through (3).

(1) For each gaseous and liquid feedstock and product, measure the volume or mass used or produced each calendar month with a flow meter by following the procedures specified in § 98.244(b)(2). Alternatively, for liquids, you may calculate the volume used or collected in each month based on measurements of the liquid level in a storage tank at least once per month (and just prior to each change in direction of the level of the liquid) following the procedures specified in § 98.244(b)(3). Fuels used for combustion purposes are not considered to be feedstocks.

(2) For each solid feedstock and product, measure the mass used or produced each calendar month by following the procedures specified in § 98.244(b)(1).

(3) Collect a sample of each feedstock and product at least once per month and determine the molecular weight (for gaseous materials when the quantity is measured in scf) and carbon content of each sample according to the procedures of § 98.244(b)(4). If multiple valid molecular weight or carbon content measurements are made during the monthly measurement period, average them arithmetically. However, if a particular liquid or solid feedstock is delivered in lots, and if multiple deliveries of the same feedstock are received from the same supply source in a given calendar month, only one representative sample is required. Alternatively, you may use the results of analyses conducted by a feedstock supplier, or product customer, provided the sampling and analysis is conducted at least once per month using any of the procedures specified in § 98.244(b)(4).

(4) If you determine that the monthly average concentration of a specific compound in a feedstock or product is greater than 99.5 percent by volume or mass, then as an alternative to the sampling and analysis specified in paragraph (c)(3) of this section, you may determine molecular weight and carbon content in accordance with paragraphs (c)(4)(i) through (iii) of this section.

(5) Calculate the CO₂ mass emissions for each petrochemical process unit using Equations X-1 through X-4 of this section.

(i) Gaseous feedstocks and products. Use Equation X-1 of this section to calculate the net annual carbon input or output from gaseous feedstocks and products. Note that the result will be a negative value if there are no gaseous feedstocks in the process but there are gaseous products.

Where:

C_g = Annual net contribution to calculated emissions from carbon (C) in gaseous materials, including streams containing CO₂ recovered for sale or use in another process (kg/yr).

(F_gf)_i,n = Volume or mass of gaseous feedstock i introduced in month “n” (scf or kg). If you measure mass, the term (MW_f)_i,n/MVC is replaced with “1”.

(CC_gf)_i,n = Average carbon content of the gaseous feedstock i for month “n” (kg C per kg of feedstock).

(MW_f)_i,n = Molecular weight of gaseous feedstock i in month “n”(kg/kg-mole).

MVC = Molar volume conversion factor (849.5 scf per kg-mole at 68 °F and 14.7 pounds per square inch absolute or 836.6 scf/kg-mole at 60 °F and 14.7 pounds per square inch absolute).

(P_gp)_i,n = Volume or mass of gaseous product i produced in month “n” (scf or kg). If you measure mass, the term (MW_p)_i,n/MVC is replaced with “1”.

(CC_gp)_i,n = Average carbon content of gaseous product i, including streams containing CO₂ recovered for sale or use in another process, for month “n” (kg C per kg of product).

(MW_p)_i,n = Molecular weight of gaseous product i in month “n” (kg/kg-mole).

j = Number of feedstocks.

k = Number of products.

(ii) Liquid feedstocks and products. Use Equation X-2 of this section to calculate the net carbon input or output from liquid feedstocks and products. Note that the result will be a negative value if there are no liquid feedstocks in the process but there are liquid products.

Where:

C_l = Annual net contribution to calculated emissions from carbon in liquid materials, including liquid organic wastes (kg/yr).

(F_lf)_i,n = Volume or mass of liquid feedstock i introduced in month “n” (gallons or kg).

(CC_lf)_i,n = Average carbon content of liquid feedstock i for month “n” (kg C per gallon or kg of feedstock).

(P_lp)_i,n = Volume or mass of liquid product i produced in month “n” (gallons or kg).

(CC_lp)_i,n = Average carbon content of liquid product i, including organic liquid wastes, for month “n” (kg C per gallon or kg of product).

j = Number of feedstocks.

k = Number of products.

(iii) Solid feedstocks and products. Use Equation X-3 of this section to calculate the net annual carbon input or output from solid feedstocks and products. Note that the result will be a negative value if there are no solid feedstocks in the process but there are solid products.

Where:

C_s = Annual net contribution to calculated emissions from carbon in solid materials (kg/yr).

(F_sf)_i,n = Mass of solid feedstock i introduced in month “n” (kg).

(CC_sf)_i,n = Average carbon content of solid feedstock i for month “n” (kg C per kg of feedstock).

(P_sp)_i,n = Mass of solid product i produced in month “n” (kg).

(CC_sp)_i,n = Average carbon content of solid product i in month “n” (kg C per kg of product).

j = Number of feedstocks.

k = Number of products.

(iv) Annual emissions. Use the results from Equations X-1 through X-3 of this section, as applicable, in Equation X-4 of this section to calculate annual CO₂ emissions.

Where:

CO₂ = Annual CO₂ mass emissions from process operations and process off-gas combustion (metric tons/year).

0.001 = Conversion factor from kg to metric tons.

44 = Molecular weight of CO₂ (kg/kg-mole).

12 = Atomic weight of carbon (C) (kg/kg-mole).

(1) Except as specified in paragraphs (d)(2) and (d)(5) of this section, calculate CO₂ emissions using the Tier 3 or Tier 4 methodology in subpart C of this part.

(2) You may use either Equation C-1 or Equation C-2a in subpart C of this part to calculate CO₂ emissions from combustion of any ethylene process off-gas streams that meet either of the conditions in paragraphs (d)(2)(i) or (d)(2)(ii) of this section (for any default values in the calculation, use the defaults for fuel gas in Table C-1 of subpart C of this part). Follow the otherwise applicable procedures in subpart C to calculate emissions from combustion of all other fuels in the combustion unit.

(3) Except as specified in paragraph (d)(5) of this section, calculate CH₄ and N₂O emissions using the applicable procedures in § 98.33(c) for the same tier methodology that you used for calculating CO₂ emissions.

(4) You are not required to use the same Tier for each stationary combustion unit that burns ethylene process off-gas.

(5) For each flare, calculate CO₂, CH₄, and N₂O emissions using the methodology specified in §§ 98.253(b)(1) through (b)(3).